Moscow, Moscow, Russian Federation
graduate student from 01.01.2020 to 01.01.2023
Moscow, Moscow, Russian Federation
Moscow, Moscow, Russian Federation
Moscow, Moscow, Russian Federation
from 01.01.2015 to 01.01.2021
Moscow, Moscow, Russian Federation
UDK 616 Патология. Клиническая медицина
GRNTI 76.29 Клиническая медицина
Subject. Ceramics based on zirconia can fluoresce through the additional application of fluorescent glazes, fluorescent dyes, as well. To date, there are no methods for assessing the fluorescence of dental materials used in prosthetics. The aim –– Development of a method for quantitative determination of the fluorescence intensity of dental prosthetic materials. Methodology. The study was conducted in the laboratory of the Faculty of Physics of Moscow State University. Fluorescence was excited by an ultraviolet lamp. The fluorescence spectra of the samples were measured using the Ocean Optics fiber optic spectrofluorometer. Ceramic billets made of zirconia "Ziceram T" A2 of domestic production without and with the staining of fluorescent glaze "Ivocolor fluo", as well as natural teeth were used as samples for patients. Results. Samples of domestic zirconia acquire fluorescent properties after applying and sintering the fluorescent glaze. The varied number of layers of the applied glaze explains why the fluorescence intensity increases. The authors compare the fluorescence spectra of two natural teeth with the spectra of zirconia samples with two and three layers of glaze. The spectra coincide well with each other in pairs. A fluorescence spectrum that is similar to one of the natural tooth samples can thus be achieved by varying the number of glaze layers. Conclusions. The analysis of the fluorescence spectra of samples of zirconia from domestic production after application and sintering of fluorescent glaze shows a similar fluorescence spectrum to samples of natural teeth.
Spectrofluorometry, fluorescence, fluorescence of teeth, zirconia fluorescence, fluorescent glaze
1. [Dyakonenko EE, Verdiyan SA, Sakhabieva DA, Lebedenko IYu. Fluorescence of zirconia-based dental ceramic materials. Stomatologiya. 2021;100(3):109-114.] (In Russ.) https://doi.org/10.17116/stomat2021100031109
2. [S.A.Gorban, E.A. Mikhaleva, V.N. Poltanov, V.I. Stepkin, V.P. Chuev, Reconstruction of the fluorescence effect in dental ceramics "Ultropalin" Modern orthopedic dentistry 2014;21:71-74.] (In Russ.)
3. Iñaki Gamborena, Markus B. Blatz The Gray Zone Around Dental Implants: Keys to Esthetic Success. The American journal of esthetic dentistry volume 2011;1 26-46
4. Max Schmeling Color Selection and Reproduction in Dentistry Part 2: Light Dynamics in Natural Teeth J. Dent. Sc. | No.18-2: 1253-2420, 2016. ISSN:1659-1046. 23
5. Takashi nakamura, Shinya Okamura, Hisataka Nishida, Hirofumi Usami, Yoshiro Nakano, Kazumichi Wakabayashi, Tohru Sekino and Hirofumi Yatani Fluorescence of thulium-doped translucent zirconia Dental Materials Journal 2018;37:1010-1016 doihttps://doi.org/10.4012/dmj.2017-384
6. Claudia Angela Maziero Volpato; Filipe Samuel Silva; Filipe Samuel Silva Fluorescence of natural teeth and restorative materials, methods for analysis and quantification: A literature review J Esthet Restor Dent. 2018;30: 397- 407. DOI:https://doi.org/10.1111/jerd.12421
7. Arndt Happe, Verena Schulte-Mattler, Christian Strassert, Michael Naumann, Michael Stimmelmayr, Joachim E. Zöller, Daniel Rothamel In Vitro Color Changes of Soft Tissues Caused by Dyed Fluorescent Zirconia and Nondyed, Nonfluorescent Zirconia in Thin Mucosa Int J Periodontics Restorative Dent 2013;33: e1-e8 doi:https://doi.org/10.11607/prd.1303
8. Caroline Freitas Rafael, Paulo Francisco Cesar, Marcio Frede, Ricardo de Souza Magini, Anja Liebermann,Cl√°udia Angela Maziero Volpato Impact of laboratory treatment with coloring and fluorescent liquids on the optical properties of zirconia before and after accelerated aging The Journal of Prosthetic Dentistry, 120 (2018) 276-281
9. Monsénégo G, Burdairon G, Clerjaud B. Fluorescence of dental porcelain. J Prosthet Dent. 1993;69(1):106-113. doihttps://doi.org/10.1016/0022-3913(93)90249-n
10. Takahashi MK, Vieira S, Rached RN, de Almeida JB, Aguiar M, de Souza EM. Fluorescence intensity of resin composites and dental tissues before and after accelerated aging: a comparative study. Oper Dent. 2008;33(2):189-195. doihttps://doi.org/10.2341/07-74
11. Stübel H. Die fluoreszenz tierischer gewebe in ultraviolettem licht. Arch Ges Physiol. 1921;142:1-14.
12. Johan A. Figueria, Edward McLaren, Sean Park The essence of fluorescence 2015; 30(4) 82-92
13. Ten Bosch JJ, Zijp JR. Optical properties of dentin. In: Thylstrup A, Leach SA, Qvist V, editors. Dentine and dentine reactions in the oral cavity. Oxford, England: IRL Press; 1987. p. 59 - 65.
14. Zijp JR, Ten Bosch JJ. Theoretical model for scattering of light by dentin and comparison with measurements. Applied Optics 1993; 32: 411 - 415.
15. Ko CC, Tantbirojn D, Wang T, Douglas WH. Optical scattering power for characterization of mineral loss. Journal of Dental Research 2000; 79: 1584 - 1589.
16. Spitzer D, Ten Bosch JJ. The absorption and scattering of light in bovine and human enamel. Calcified Tissue Research 1975; 17: 129 - 137.
17. Zijp JR, Ten Bosch JJ, Groenhuis RAJ. HeNe-laser scattering by human dental enamel. Journal of Dental Research 1995; 74: 1891 - 1898.
18. Hefferren JJ, Hall JB, Bennett E. Luminescence as a tool to study enamel interactions. In: Fearnhead RW, Stack MV, editors. Tooth enamel II. Bristol: John Wright; 1971. p. 161 - 165.
19. Perry A, Biel M, DeJongh O, Hefferren JJ. A comparative study of the native fluorescence of human dentine and bovine skin collagens. Archives of Oral Biology 1969;14: 1193 - 1211.
20. Fujimoto D, Akiba K, Makamura N. Isolation and characterization of a fluorescent material in bovine achilles tendon collagen. Biochemical and Biophysics Research Communications 1977; 76: 1124 - 1129.
21. Booij M, Ten Bosch JJ. A fluorescent compound in bovine dental enamel matrix compared with synthetic dityrosine. Archives of Oral Biology 1982; 27: 417 - 421.
22. Seghi RR, Johnston WM, O’Brien WJ. Performance assessment of colorimetric devices on dental porcelains. Journal of Dental Research 1989; 68: 1755 - 1759.
23. Paul S, Peter A, Pietroban N, Hammerle CHF. Visual and spectrophotometric shade analysis of human teeth. Journal of Dental Research 2002; 81: 578 - 582.
24. Okubo SR, Kanawati A, Richards MW, Childress S. Evaluation of visual and instrument shade matching. Journal of Prosthetic Dentistry 1998; 80: 642 - 648.
25. Schwabacher WB, Goodkind RJ. Three-dimensional color
26. Mualla S. Fluorescence and dentistry. J Dent Med Scie. 2016;15(3):65-75. https://doi.org/10.9790/0853-1503096575
27. Lakowicz R. Principles of Fluorescence Spectroscopy. 3rd ed. New York: Springer; 2006.
28. Kauling A, Volpato C, Carvalho O, Pereira M, Güth J. Translucency, contrast ratio and fluorescence of esthetic materials. Dental Materials. 2018;e127.
29. Sedighe Sadat Hashemikamangar, Sara Valizadeh, Alireza Mahmoudi Nahavandi, Masoomeh Hasani Tabatabaei, Marzieh Daryadar Effect of Thickness on Fluorescence of Some Clinical Dental Ceramics Front Dent. 2021; 18: 41. Published online 2021 Nov 25. doi:https://doi.org/10.18502/fid.v18i41.8013
30. Meller C, Klein C. Fluorescence properties of commercial composite resin restorative materials in dentistry. Dent Mater J. 2012 Nov;31(6):916-23.
31. Takahashi MK, Vieira S, Rached RN, de Almeida JB, Aguiar M, de Souza EM. Fluorescence intensity of resin composites and dental tissues before and after accelerated aging: a comparative study. Oper Dent. 2008 Mar-Apr;33(2):189-95.
32. Lee YK. Fluorescence properties of human teeth and dental calculus for clinical applications. J Biomed Opt. 2015 Apr;20(4):040901.
33. Iñaki Gamborena, Markus B. Blatz The Gray Zone Around Dental Implants: Keys to Esthetic Success // The American journal of aesthetic dentistry. - 2011;1:26-46. https://www.drgamborena.com/wp-content/uploads/2016/07/2011_Gamborena_PROOF.pdf
34. Max Schmeling. Color Selection and Reproduction in Dentistry. Part 2: Light Dynamics in Natural Teeth // J. Dent. Sc. - 2016;18-2:1253-2420. DOIhttps://doi.org/10.15517/ijds.v0i0.24493
35. Takashi Nakamura, Shinya Okamura, Hisataka Nishida, Hirofumi Usami, Yoshiro Nakano, Kazumichi Wakabayashi, Tohru Sekino and Hirofumi Yatani. Fluorescence of thulium-doped translucent zirconia // Dental Materials Journal. - 2018;37:1010-1016. doihttps://doi.org/10.4012/dmj.2017-384
36. Claudia Angela Maziero Volpato, Filipe Samuel Silva, Filipe Samuel Silva. Fluorescence of natural teeth and restorative materials, methods for analysis and quantification: A literature review // J Esthet Restor Dent. - 2018;30:397-407. DOI:https://doi.org/10.1111/jerd.12421
37. Arndt Happe, Verena Schulte-Mattler, Christian Strassert, Michael Naumann, Michael Stimmelmayr, Joachim E. Zöller, Daniel Rothamel. In Vitro Color Changes of Soft Tissues Caused by Dyed Fluorescent Zirconia and Nondyed, Nonfluorescent Zirconia in Thin Mucosa // Int J Periodontics Restorative Dent. - 2013;33:e1-e8. doi:https://doi.org/10.11607/prd.1303
38. Caroline Freitas Rafael, Paulo Francisco Cesar, Marcio Frede, Ricardo de Souza Magini, Anja Liebermann, Claudia Angela Maziero Volpato. Impact of laboratory treatment with coloring and fluorescent liquids on the optical properties of zirconia before and after accelerated aging // The Journal of Prosthetic Dentistry. - 2018;120:276-281. DOI:https://doi.org/10.1016/j.prosdent.2017.10.017
39. D'yakonenko E.E., Verdiyan S.A., Sahabieva D.A., Lebedenko I.Yu. Fluorescenciya stomatologicheskih keramicheskih materialov na osnove dioksida cirkoniya. Stomatologiya. 2021;100(3):109-114. [E.E. Dyakonenko, S.A. Verdiyan, D.A. Sakhabieva, I.Yu. Lebedenko. Fluorescence of zirconia-based dental ceramic materials. Dentistry. 2021;100(3):109-114. (In Russ.)]. https://doi.org/10.17116/stomat2021100031109
40. Monsénégo G., Burdairon G., Clerjaud B. Fluorescence of dental porcelain // J Prosthet Dent. - 1993;69(1):106-113. doihttps://doi.org/10.1016/0022-3913(93)90249-n
41. Gorban' S.A., Mihaleva E.A., Poltanov V.N., Stepkin V.I., Chuev V.P. Vossozdanie effekta fluorescencii v stomatologicheskoy keramike «Ul'tropalin». Sovremennaya ortopedicheskaya stomatologiya. 2014;21:71-74. [S.A. Gorban, E.A. Mikhaleva, V.N. Poltanov, V.I. Stepkin, V.P. Chuev. Reconstruction of the fluorescence effect in dental ceramics "Ultropalin". Modern orthopedic dentistry. 2014;21:71-74. (In Russ.)]. https://vladmiva.ru/publications/vossozdanie-effekta-fluorestsentsii-v-stomatologicheskoy-keramike-ultropalin/
42. Takahashi M.K., Vieira S., Rached R.N., de Almeida J.B., Aguiar M., de Souza E.M. Fluorescence intensity of resin composites and dental tissues before and after accelerated aging: a comparative study // Oper Dent. - 2008;33(2):189-195. doihttps://doi.org/10.2341/07-74
43. Stübel H. Die fluoreszenz tierischer gewebe in ultraviolettem licht // Arch Ges Physiol. - 1921;142:1-14. https://doi.org/10.1007/BF01680690
44. Johan A. Figueria, Edward McLaren, Sean Park. The essence of fluorescence // Journal of cosmetic dentistry. - 2015; 30(4):82-92. https://thinkblue.me/Pubs/PDFs/Ess_of_Fluorescence.pdf
45. Ten Bosch J.J., Zijp J.R. Optical properties of dentin // Dentine and dentine reactions in the oral cavity. Oxford, England : IRL Press. 1987:59-65. https://www.goodreads.com/book/show/7340020-dentine-and-dentine-reactions-in-the-oral-cavity
46. Zijp J.R., Ten Bosch J.J. Theoretical model for scattering of light by dentin and comparison with measurements // Applied Optics. - 1993;32:411-415. DOI:https://doi.org/10.1364/AO.32.000411
47. Ko C.C., Tantbirojn D., Wang T., Douglas W.H. Optical scattering power for characterization of mineral loss // Journal of Dental Research. - 2000;79:1584-1589. doi:https://doi.org/10.1177/00220345000790081001.
48. Spitzer D., Ten Bosch J.J. The absorption and scattering of light in bovine and human enamel // Calcified Tissue Research. - 1975;17:129-137. doi:https://doi.org/10.1007/BF02547285.
49. Zijp J.R., Ten Bosch J.J., Groenhuis R.A.J. HeNe-laser scattering by human dental enamel // Journal of Dental Research. - 1995;74:1891-1898. doi:https://doi.org/10.1177/00220345950740121301.
50. Perry A., Biel M., DeJongh O., Hefferren J.J. A comparative study of the native fluorescence of human dentine and bovine skin collagens // Archives of Oral Biology. - 1969;14:1193-1211. doi:https://doi.org/10.1016/0003-9969(69)90158-7.
51. Fujimoto D., Akiba K., Makamura N. Isolation and characterization of a fluorescent material in bovine achilles tendon collagen // Biochemical and Biophysics Research Communications. - 1977;76:1124-1129. doi:https://doi.org/10.1016/0006-291x(77)90972-x.
52. Booij M., Ten Bosch J.J. A fluorescent compound in bovine dental enamel matrix compared with synthetic dityrosine // Archives of Oral Biology. - 1982;27:417-421. doi:https://doi.org/10.1016/0003-9969(82)90152-2.
53. Seghi R.R., Johnston W.M., O’Brien W.J. Performance assessment of colorimetric devices on dental porcelains // Journal of Dental Research. - 1989;68:1755-1759. doi:https://doi.org/10.1177/00220345890680120701.
54. Paul S., Peter A., Pietroban N., Hammerle C.H.F. Visual and spectrophotometric shade analysis of human teeth // Journal of Dental Research. - 2002;81:578-582. doi:https://doi.org/10.1177/154405910208100815.
55. Okubo S.R., Kanawati A., Richards M.W., Childress S. Evaluation of visual and instrument shade matching // Journal of Prosthetic Dentistry. - 1998;80:642-648. doi:https://doi.org/10.1016/s0022-3913(98)70049-6.
56. Schwabacher W.B., Goodkind R.J. Three-dimensional color coordinates of natural teeth compared with three shade guides // J Prosthet Dent. - 1990;64(4):425-431. doi:https://doi.org/10.1016/0022-3913(90)90038-e.
57. Mualla S. Fluorescence and dentistry // J Dent Med Scie. - 2016;15(3):65-75. https://doi.org/10.9790/0853-1503096575
58. Lakowicz R. Principles of Fluorescence Spectroscopy. 3rd ed. New York : Springer. 2006. https://link.springer.com/book/10.1007/978-0-387-46312-4
59. Kauling A., Volpato C., Carvalho O., Pereira M., Güth J. Translucency, contrast ratio and fluorescence of esthetic materials // Dental Materials. - 2018:e127. https://doi.org/10.1016/j.dental.2018.08.264
60. Sedighe Sadat Hashemikamangar, Sara Valizadeh, Alireza Mahmoudi Nahavandi, Masoomeh Hasani Tabatabaei, Marzieh Daryadar. Effect of Thickness on Fluorescence of Some Clinical Dental Ceramics // Front Dent. - 2021;18:41. doi:https://doi.org/10.18502/fid.v18i41.8013
61. Meller C., Klein C. Fluorescence properties of commercial composite resin restorative materials in dentistry // Dent Mater J. - 2012;31(6):916-923. doi:https://doi.org/10.4012/dmj.2012-079.
62. Takahashi M.K., Vieira S., Rached R.N., de Almeida J.B., Aguiar M., de Souza E.M. Fluorescence intensity of resin composites and dental tissues before and after accelerated aging: a comparative study // Oper Dent. - 2008;33(2):189-195. doi:https://doi.org/10.2341/07-74.
63. Lee Y.K. Fluorescence properties of human teeth and dental calculus for clinical applications // J Biomed Opt. - 2015;20(4):040901. doi:https://doi.org/10.1117/1.JBO.20.4.040901.
